If X-atoms are present at alternate corners and at body centre of a cube and Y-atoms are present at 1/3rd of face centers then what will be the empirical formula?
1. X2.5Y
2. X5Y2
3. X1.5Y
4. X3Y2
Subtopic:  Voids, Radius Ratio & Coordination Number |
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The percentage of \(Fe^{2+} \) ions in \(Fe_{0.93}O \) is: 

1. 15 %
2. 85 %
3. 65 %
4. 35 %
Subtopic:  Imperfections in Solids & Semiconductors |
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In a non-stoichiometry compound, M0.83O, M exists in two states +2 and +3. Calculate the percentage of M2+ ion in the compound?

1. 59 %
2. 64 %
3. 52 %
4. 68 %
Subtopic:  Imperfections in Solids & Semiconductors |
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The unit cell of copper corresponds to a face-centred cube of edge length 3.596 Å with one copper atom at each lattice point. The calculated density of copper in kg/m3 is-
[Molar mass of Cu : 63.54 g ; Avogadro Number = 6.022× 1023]
1. 9076
2. 9100
3. 8994
4. 9087

Subtopic:  Density & Packing Fraction |
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The coordination number of an atom in a body-centered cubic structure is-.
[Assume that the lattice is made up of atoms.]

1. 4

2. 6

3. 8

4. 12

Subtopic:  Voids, Radius Ratio & Coordination Number |
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The number of octahedral voids per lattice site in a lattice is-

1. 2

2. 1

3. 4

4. 0

Subtopic:  Voids, Radius Ratio & Coordination Number |
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An element with molar mass 2.7 × 10–2 kg mol–1 forms cubic unit cell with edge length 405 pm. If its density is 2.7 × 103 kg m–3 , the radius of the element in  × 10–12 m is approximately- 

1. 148

2. 143

3. 140

4. 152

Subtopic:  Density & Packing Fraction |
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A diatomic molecule X2 has a body-centred cubic (bcc) structure with a cell edge of 300 pm. The density of the molecule is 6.17 g cm–3 . The number of molecules present in 200 g of X2 is-
(Avogadro constant (NA) = 6 × 1023 mol–1)
1. 8 NA
2. 40 NA
3. 4 NA
4. 2 NA

Subtopic:  Density & Packing Fraction |
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A crystal is made up of metal ions 'M1' , 'M2', and oxide ions. Oxide ions form a CCP lattice structure. The cation 'M1' occupies 50% of octahedral voids and the cation 'M2' occupies 12.5% of tetrahedral voids of oxide lattice. The oxidation numbers of 'M1' and'M2' are, respectively :
1. +2, +4
2. +3, +1
3. +1, +3
4. +4, +2

Subtopic:  Voids, Radius Ratio & Coordination Number |
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Element ‘B’ forms ccp structure and ‘A’ occupies half of the octahedral voids, while oxygen atoms occupy all the tetrahedral voids. The structure of bimetallic oxide is -
1.  A2BO4
2. A4B2O
3. AB2O4
4. A2B2O

Subtopic:  Voids, Radius Ratio & Coordination Number |
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