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| List-I (Reactions) |
List-II (Products) |
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I. | \(\small\mathrm{{\left({CH}_3\right)_2 {C}={O}+{CO}_2+\mathrm{H}_2 {O} }}\) |
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IV. | \(\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{OH} \) |

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Determine the IUPAC name of the compound with the molecular formula C₆H₁₄ that contains two tertiary carbon atoms.
1. 2-Methyl pentane
2. 2, 3-Dimethylbutane
3. 2, 2-Dimethylbutane
4. n-Hexane
| Statement I: | The boiling point of three isomeric pentanes follows the order, \(\small\text { n-Pentane }>\text { Isopentane }>\text { Neopentane }\) |
| Statement II: | When branching increases, the molecule attains the shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. |
| 1. | \((CH_3)_3C(CH_2)_2CH_3~~~~~~~~~~~~~\) |
| 2. | 4-isobutyl heptane |
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| 4. |
| 1. | 33% p character and are at a lower energy level than the electron pair in the \(\sigma -\) bond. |
| 2. | 50% p character and are at a higher energy level than the electron pair in the \(\sigma -\) bond. |
| 3. | 100% p character and are at a lower energy level than the electron pair in the \(\sigma -\) bond. |
| 4. | 100% p character and are at a higher energy level than the electron pair in the \(\sigma -\) bond. |
The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is:
| 1. | The eclipsed conformation of ethane is more stable than staggered conformation because eclipsed conformation has no torsional strain. |
| 2. | The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has a torsional strain. |
| 3. | The staggered conformation of ethane is more stable than eclipsed conformation because staggered conformation has no torsional strain. |
| 4. | The staggered conformation of ethane is less stable than eclipsed conformation because staggered conformation has a torsional strain. |
An unsaturated hydrocarbon 'A' reacts with two molecules of H2 and upon reductive ozonolysis A gives butane-1,4-dial, ethanal, and propanone.
The IUPAC name of A is:
1. 2-Methylocta-2,6-diene
2. 2-Methylocta-1,5-diene
3. 3-Methylocta-2,6-diene
4. 2-Methylocta-1,6-diene
The most suitable reagent for the following conversion is:
| 1. | Hg2+/ H+, H2O | 2. | Na/liquid NH3 |
| 3. | H2, Pd/C, quinoline | 4. | Zn/HCl |