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Please note that this rule is applicable in SN1 reactions and not SN2 which was being discussed. In SN2 reaction, the nuclephile will attack the less bulky side as discussed in the previous rule (rule 1). So, the products for SN2 reaction in this case will be different to what will be in SN1 reaction being discussed now.
SN1 reaction of Ethyl tert-butyl ether with HBr will give Tert-butyl bromide and Ethanol.
SN2 reaction of Ethyl tert-butyl ether with HBr will give Tert-butyl alcohol and Ethyl bromide.
Related Practice Questions :
Which position will be attacked most rapidly by the nitronium ion (-NO2)+ when the compound undergoes nitration with HNO3/H2SO4 :-
1. A
2. B
3. C
4. D
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Which one of the following undergoes nucleophilic aromatic substitution at the fastest rate? (1)
(2)
(3)
(4)
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Which of the following meta-directing substituents is the most deactivating in aromatic substitution?
1.
–SO3H
2.
–COOH
3.
–NO2
4.
–C≡N
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Among cyclohexanol (I), acetic acid (II), 2, 4, 6-trinitrophenol (III) and phenol (IV) the correct order of decreasing acidic character will be:
1.
III>II>IV>I
2.
II>III>I>IV
3.
II>III>IV>I
4.
III>IV>II>I
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Following is the list of some aromatic compounds. Select the correct sequence of decreasing order of reactivity for electrophilic aromatic substitution reaction using the answer codes given below:
a.
b.
c.
d.
Answer codes :
1. a d b c
2. c d b a
3. a b d c
4. a b c d
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