Consider the following statements:

(i) Alkene is more reactive than alkyne for electrophilic addition reaction.

(ii) Alkyne gives nucleophilic as well as electrophilic addition reaction.

(iii) Alkyne is more reactive than alkene for nucleophilic addition reaction.

(iv) For electrophilic addition reaction, RI of alkyne is alkyl carbonation.

Of these, correct statements are:

(1) only (i)

(2) (i) and (ii)

(3) (i), (ii) and (iv)

(4) (i), (ii) and (iii)

Subtopic:  Reaction Intermediates |
Level 3: 35%-60%
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In the given reaction

 

N2 gasCH2N2/

The product will be:

1. 

2. 

3. Mixture of 1 and 2 

4. CH3-CH2-CH2-CH2-CH3

Subtopic:  Addition Reaction of C=C |
 67%
Level 2: 60%+
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Which compound is least reactive for nucleophilic addition reaction?

(1) C6H5CHO

(2) C6H5-C||O-CH3

(3) C6H5-C||O-C6H5

(4) CH3-C||O-CH3

Subtopic:  Addition Reaction of C=N, C=0 |
 62%
Level 2: 60%+
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Arrange the reactivity of given carbonyl compounds in decreasing order for addition reaction:

(i) CH2Br-CHO

(ii) CH2Cl-CHO

(iii) CH2I-CHO

(iv) CH3-CHO

Select the correct answer from the codes given below:

Codes:

(1) (iv), (iii), (ii), (i)

(2) (ii), (i), (iii), (iv)

(3) (ii), (i), (iv), (iii)

(4) (i), (ii), (iii), (iv)

Subtopic:  Directive Effect of functional grp |
 65%
Level 2: 60%+
Hints

Arrange the reactivity of the given compounds in decreasing order for addition followed by elimination reaction:

(i) p-Cl-C6H4-CHO

(ii) p-Br-C6H4-CHO

(iii) p-F-C6H4-CHO

(iv) p-I-C6H4-CHO

Select the correct answer from the codes given below:

Codes:

(1) (i), (iii), (ii), (iv)

(2) (i), (iii), (iv), (ii)

(3) (iii), (i), (iv), (ii)

(4) (iii), (i), (ii), (iv)

Subtopic:  Directive Effect of functional grp |
 74%
Level 2: 60%+
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Which compound will form Schiff base with carbonyl compounds?

(1) p-amines 

(2) sec-amines

(3) bydroxylamine

(4) Hydrazine

Subtopic:  Reagents |
Level 3: 35%-60%
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Gem di-ether is obtained by:

(i) aldehyde, alcohol, H

(ii) ketone, alcohol, H

(iii) ketone, alcohol, OH

(iv) aldehyde, alcohol, OH

Select the correct answer from the codes given below:

Codes:

(1) (i), (ii), (iii) and (iv)

(2) (i), (ii) and (iv)

(3) (iii) and (iv)

(4) (i) and (ii)

Subtopic:  SN1 & SN2 Reactions | Reactions in Ether & Alcohol |
Level 3: 35%-60%
Hints

Which among the following compounds will give addition reaction with water?

(i) CH3-CH=CH2

(ii) CH3-CCH

(iii) CCl3-CHO

(iv) CH3-CHO

Select the correct answer from the codes given below:

Codes:

(1) (i), (ii), (iii)

(2) (i) and (ii)

(3) (i), (ii), (iv)

(4) only (iii)

Subtopic:  Addition Reaction of C=N, C=0 |
Level 3: 35%-60%
Hints

Which among the following compounds is used for protection of carbonyl groups?

1. HCN

2. CH3OH

3. 

4.  C2H5OH

Subtopic:  Addition Reaction of C=N, C=0 |
 64%
Level 2: 60%+
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In the given reaction,

CH3-CNH2O/(A)H2O/H/(B)

(A) and (B) respectively are:

(1) O

CH3-C-NH2andCH3COOH

(2) CH3COONH4andCH3COOH

(3) CH3CONH2andCH3COONH4

(4) CH3-CH=NHandCH3COOH

Subtopic:  SN1 & SN2 Reactions |
 67%
Level 2: 60%+
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